Alkene Reaction

 

The Summary of Alkene Reaction in Markovikov's Rule

The double bond in alkene is electron rich and enable to react with any electrophile such as H+. Two carbons that have the double bond will be open up. The rule to which carbon make a bond depending on Markovnikov's rule.

   Markovnikov's rule. - Hydrogen bonds to the most hydrogenated carbon. 

From this chapter on, many reactions will be discuss and the best starting point is from the summary to memorize.

Oxidative Cleavage: 2 examples with  / warm condition

Step 1 using your thumb to cover the right end of alkene see thumb as an oxygen and draw the first product.

Step 2: cover the left end of double bond with thumb and again see the thumb as an oxygen and draw the product

Step 3:: If there is aldehyde,  convert it to carboxylic acid.

Remember Aldehyde has to convert to carboxylic acid because KMnO4 is a very strong reducing agent!!

oxidative cleavage

Anti-Markovnikov

   (Syn addition)

Anti -hydroxylation

Syn- hydroxylation

Oxidative Cleavage

 

 

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